The goal of brushing your teeth isn’t to kill bacteria outright – it’s to remove deposits of food and plaque that allows bacteria to thrive and multiply, and excrete lots of acid that damages your teeth.
Actually sterilizing your mouth would be hard to do and require very high concentrations of alcohol. And it’s pointless because new bacteria would colonize your mouth in no time. Not to mention, there are plenty of good bacteria in your mouth that are important for good oral health and hygiene, for instance because they out-compete other (bad) microbes and thus help prevent fungal infections and the like.
The ionic fluoride in saliva, in plaque, and within enamel and dentin shifts the equilibrium of demineralization-remineralization toward remineralization. Fluoride acts as a catalyst for uptake of calcium and phosphate ions and results in a greater efficiency in remineralizing the areas of enamel and dentin that have been affected by acidic attack
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